A Scientifically Vexing Condiment

 

A Scientifically Vexing Condiment


   by Adil Aftab
   Mon, 18, Dec 2021

Simply tilting a ketchup bottle is sufficient to induce its contents to flow out… eventually, but science has demonstrated that there are fewer than 17 humans alive today who possess adequate patience for that method. The other several billion of us are quickly and invariably driven to shocking acts of violence, repeatedly buffeting the bottom of a bottle to compel a splat of red ejecta, or stabbing a knife up its neck and forcibly extracting a dollop. We don’t put up with this from our other condiments. What’s ketchup’s problem?
It is a non-Newtonian fluid, like latex paint, toothpaste, blood, xanthan gum solutions, and some printer inks.

Most fluids are Newtonian and all alike since their viscosity is independent of stress. Non-Newtonian fluids (NNFs), on the other hand, are defined by odd reactions to stress. Some become more viscous, while others become less so. Some change viscosity depending on how much or how long the stress is applied. When stress is applied to any NNF, the fluid develops internal layers that each has a different viscosity.



Oobleck, a simple combination of corn starch and water named after a goo in a Dr. Seuss book, is a common homemade alternative to Play-Doh and an NFF. The memory of playing with Oobleck led an Air Force researcher in 2017 to experiment with different NNFs to create armor. The Air Force discovered at least one NNF that hardens so thoroughly and quickly in response to great forces that it can literally stop bullets.

That explains why ketchup seems almost willfully recalcitrant to exit its container, but it helps naught with the extraction. Every ketchup maker has figured out that if you put ketchup in a plastic bottle and squeeze, the column of ketchup along the central axis of the bottle is the least viscous and squirts out easily. For those of you eager to flaunt your grasp of NNFs, however, there’s a new trick to dealing with glass bottles of ketchup.

How a given NNF layer moves compared with an adjoining layer is referred to as shear. Increasing viscosity is “dilatant,” while decreasing viscosity is “shear thinning.” Heinz discovered the optimum place to apply force to a glass ketchup bottle to induce shear thinning. Look for a debossed “57” on the necks of Heinz ketchup bottles and tap there.


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